Gold(I)-catalyzed intermolecular addition of phenols and carboxylic acids to olefins.
نویسندگان
چکیده
Ph3PAuOTf can catalyze efficient intermolecular addition of phenols and carboxylic acids to olefins under relatively mild conditions.
منابع مشابه
Brønsted acid catalyzed addition of phenols, carboxylic acids, and tosylamides to simple olefins.
Intermolecular addition of phenols, carboxylic acids, and protected amines to inert olefins can be catalyzed by low concentrations (1-5%) of triflic acid. Functional groups, such as the methoxyl substitution on aromatics, could be tolerated if the concentration of triflic acid and the reaction temperature are controlled appropriately. This reaction provides one of the simplest olefin addition m...
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 127 19 شماره
صفحات -
تاریخ انتشار 2005